Silylated Phosphines and Phosphoranimines.

reportActive / Technical Report | Accession Number: ADA173455 | Open PDF

Abstract:

The N-silylphosphoranimines E.G., Me3SiNP OCH2CF3Me2 undergo a variety of reactions including deprotonationsubstitution of the P-Me groups, transilylation, and condensation with reactive phosphines. Some new 1,2-addition and oxidation reactions of the PC systems, R2NPCHR, R2NPNRCHR, and R2NPCR-CHCHR R SiMe3 are also reported. Keywords methylenephosphine.

Author(s):
Neilson, Robert H. ; Boyd, Bruce A. ; Dubois, Donn A. ; Hani, Rahim ; Scheide, Gary M.
Author Organization(s):
TEXAS CHRISTIAN UNIV FORT WORTH DEPT OF CHEMISTRY
Descriptive Note:
Technical rept.,
Pagination:
0006

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TCU/DC/TR-86-02
Contract/Grant Number(s):
N00014-79-C-0632
 Subject Terms
Joint Capability Areas:
JCA_1.2_Force Preparation; JCA_1_Force Support
Modernization Areas:
Microelectronics
Communities of Interest:
Materials and Manufacturing Processes
Descriptor(s):
*CHEMICAL REACTIONS, *PHOSPHINE, *IMINES, *ORGANIC PHOSPHORUS COMPOUNDS, REACTIVITIES, METHYLENES, SILICON COMPOUNDS, OXIDATION REDUCTION REACTIONS, CONDENSATION, ADDITION REACTIONS, SUBSTITUTION REACTIONS
Field(s)/Group(s):
Organic Chemistry
Keyword(s):
WUNR056123
Report Date:
1986 Oct 10