Gallium-Nitrogen Compounds Prepared by Dihydronaphthalene Structures of (PhMe2CCH2GaNH(t-Bu)2 and(H4C6)Me2CCH2GaNH(t-Bu)2Ga(CH2CMe2Ph)2.

Beachley, O. T., Jr.; Noble, Matthew J.; Churchill, Melvyn R.; Lake, Charles H.

Gallium-Nitrogen Compounds Prepared by Dihydronaphthalene Structures of (PhMe2CCH2GaNH(t-Bu)2 and(H4C6)Me2CCH2GaNH(t-Bu)2Ga(CH2CMe2Ph)2.

Active / Technical Report | Accession Number: ADA353952 |

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Abstract:

The dihydronaphthalene elimination reaction between Na2C10H8GaR2Cl2 R CH2CMe3, CH2CMe2Ph and t-BuNH2 provided a room temperature route to R2GaNHt-Bu2. However, when GaCH2CMe2Ph3 and t-BuNH2 were reacted at 140 - 150C, C6H5CMe3 was eliminated and the product was H4C6Me2CCH2GaNHt-Bu2GaCH2CMe2Ph2, a galliumIII amide with one GaC4 metallocyclic ring, rather than PhMe2CCH22GaNHt- Bu2. X-ray structural studies confirmed the identity of this novel compound as well as that of the typical dimer. When the reaction temperature was increased to 210 - 230C, the product was H4C6Me2CCH2GaNHt-Bu2GaCH2CMe2C6H4, a species with two GaC4 metallocyclic rings.

Author(s):

Beachley, O. T., Jr. ; Noble, Matthew J. ; Churchill, Melvyn R. ; Lake, Charles H.

Author Organization(s):

STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY

Supplementary Note:

DOI: 10.21236/ADA353952

Pagination:

0033

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:

Approved For Public Release

RECORD

Collection: TR

Identifying Numbers

Report Number(s):

SUNY/AB-TR-52

Contract/Grant Number(s):

N00014-96-1-0483

Monitor Series:

ONR

Subject Terms

Joint Capability Areas:

JCA_5_Command and Control

Modernization Areas:

Fully Networked C3

Communities of Interest:

Air Platforms

Descriptor(s):

*CRYSTAL STRUCTURE, *MOLECULAR STRUCTURE, *GALLIUM COMPOUNDS, *NITROGEN COMPOUNDS, THERMAL PROPERTIES, TEMPERATURE, STRUCTURAL PROPERTIES, X RAYS, RESPONSE, RINGS

Field(s)/Group(s):

Inorganic Chemistry, Organic Chemistry

Keyword(s):

*DIHYDRONAPHTHALENS

Report Date:

1998 Sep 24

Creation Date:

1998 Oct 07