Syntheses, Characterization, Crystal and Molecular Structures and Solution Properties of Et2Ga(C5H5) and EtGa(C5H5) 2.

reportActive / Technical Report | Accession Number: ADA295665 | Open PDF

Abstract:

The compounds Et2GaC5H5 and EtGaC5H52 have been prepared by ligand redistribution reactions in pentane solution between appropriate quantities of GaEt3 and GaC5H53. Both compounds have been fully characterized by elemental analyses, X-ray structural studies, cryoscopic molecular weight studies in benzene solution, mass spectroscopic studies, 1H NMR studies of solutions and 1H NMR studies of the melts. Both compounds exist as pure single compounds in the solid state. jg

Author(s):
Beachley, O. T., Jr. ; Rosenblum, Daniel B. ; Churchill, Melvyn R. ; Lake, Charles H. ; Krajkowski, Lynn M.
Author Organization(s):
STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY
Descriptive Note:
Technical rept.,
Pagination:
0038

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TR-42
Contract/Grant Number(s):
N00014-90-J-1530
Monitor Series:
ONR
 Subject Terms
Joint Capability Areas:
JCA_6.3.3_Spectrum Management; JCA_6_Net Centric; JCA_6.3_Net Management; JCA_5_Command and Control; JCA_1_Force Support; JCA_5.3_Planning; JCA_1.2_Force Preparation
Modernization Areas:
Microelectronics
Communities of Interest:
Weapons Technologies
Descriptor(s):
*CRYSTAL STRUCTURE, *SOLUTIONS(GENERAL), *GALLIUM, *MOLECULAR STRUCTURE, *ETHYL RADICALS, BENZENE, METHYL RADICALS, SYNTHESIS, STRUCTURAL ANALYSIS, MOLECULAR WEIGHT, MELTS, ORGANOMETALLIC COMPOUNDS, MASS SPECTROSCOPY, X RAYS, PURITY, HYDROCARBONS, LIGANDS, CRYOGENICS, SOLID STATE CHEMISTRY, PENTANES
Field(s)/Group(s):
Organic Chemistry, Inorganic Chemistry, Physical Chemistry, Crystallography, Atomic and Molecular Physics and Spectroscopy
Report Date:
1995 Jun 19