IR Materials Producibility

reportActive / Technical Report | Accession Number: ADA284263 | Open PDF

Abstract:

The work summarized in this report covers the eighth quarter of a program with a goal that is threefold first, to study the properties of native point defects in infrared focal-plane array IRFPA active and substrate materials second, to study the properties of native point defects in two classes of photonic materials, the wide-gap II-VI compounds ZnSe as the prototype for which impurity properties will also be calculated and the nonlinear optical materials LiNbO3 as the prototype the third, to study the properties of HgZnTe as a very-long-wave infrared VLWIR detector material. During the eighth quarter We have continued the refinement of the calculation of the tellurium antisite-mercury vacancy pair in HgCdTe. We find a binding energy of more than 1 eV. We have developed a strategy for calculating the ionization energies of defects in semiconductors, and have tested the strategy on the arsenic antisite in GaAs with good results. We have begun the calculation of the ionization energies in CdTe and ZnSe, and preliminary results are reported. Transport-related properties have been calculated for HgCdTe and HgZnTe and compared with results using the effective mass approximation.

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