Studies of the n-Alkane/Water Interface by Total Internal Reflection Second Harmonic Generation

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Abstract:

Total internal reflection second harmonic generation TIRSHG has made possible the study of a series of neat n-alkanewater interfaces. Analysis of the incident and polarization angular dependent SH response allows for determination of interfacial nonlinear molecular properties. The measured surface nonlinear susceptibilities may be indicative of a high degree of interfacial order. Total Internal Reflection Second Harmonic Generation, Neat n- alkanewater interfaces.

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