Design of Acentric Materials: X-Ray Structures of Guanidinium p-Nitro- and p-Hydroxybenzenesulfonate

reportActive / Technical Report | Accession Number: ADA264220 | Open PDF

Abstract:

Guanidinium p-nitro- and p-hydroxybenzenesulfonate crystallize in noncentros acentric space groups and exhibit second-harmonic generation. The engineering of these structures was accomplished using hydrogen bonding and the tendency to pack in centrosymmetric structures overcome by screening of the dipolar forces between arylsulfonates by charged layers of guanidinium ions. Guanidinium sulfonatesecond-harmonic generation hydrogen bondingmaterials design

Author(s):
Russell, V. A. ; Etter, M. C. ; Ward, M. D.
Author Organization(s):
MINNESOTA UNIV MINNEAPOLIS DEPT OF CHEMISTRY
Descriptive Note:
Technical rept. 1 Jun 92-31 May 93,
Pagination:
0007

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release
Distribution Statement:
Approved For Public Release; Distribution Is Unlimited.

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TR-24
Contract/Grant Number(s):
N00014-89-J-1301
Project Number(s):
4135
Monitor Series:
ONR
 Subject Terms
Joint Capability Areas:
JCA_1.2_Force Preparation; JCA_1_Force Support; JCA_1.2.3_Educating
Communities of Interest:
Air Platforms
Descriptor(s):
*HYDROGEN, *BONDING, IONS, POLARIZATION, BENZENE, CRYSTAL STRUCTURE, SYMMETRY, MOLECULAR STRUCTURE, NITRO RADICALS, HYDROXYL RADICALS, SULFONATES, ARYL RADICALS, LAYERS, SECOND HARMONIC GENERATION, MATERIALS, CHARGED PARTICLES
Field(s)/Group(s):
Organic Chemistry, Physical Chemistry, Crystallography, Atomic and Molecular Physics and Spectroscopy
Keyword(s):
*ACENTRIC MATERIALS, *GUANIDINIUM P NITROBENZENESULFONATES, PE61153N, WUNR4135010, NONCENTROSYMMETRIC SPACE GROUPS, P HYDROXYBENZENESULFONATES
Report Date:
1993 Apr 22