Electrical, Magnetic and Spectroscopic Properties of (TTF)5Fe(NO3)3

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Abstract:

Tetrathiafulvalene, TTF, reacts with Fe NO3. 9H20 to yield a dark purple charge-transfer compound with the formula TTF5FeNO33. effective magnetic moment at room temperature of 0.6 B. M. the temperature independent paramagnetism in the range 77-300 K, and the absence of an EPR signal attributable to iron, indicates low-spin iron II , with electron transfer from TTF. The g values of the parallel and perpendicular EPR lines, T, g1, g1, 300 K, 2.007, 2.010, 77K, 2.009, 2.013, and the line widths indicate that the odd electron resides on, and is delocalized over several TTFs. The conductivity at room temperature is 17 S cm-1, and the temperature dependence of the resistivity indicates semiconducting behavior of a complex nature.... tetrathiafulvalene, magnetic moment, electrical conductivity, electroparamagnetic resonance, IRONIII compound.

Author(s):
Kim, Young I. ; Hatfield, William E.
Author Organization(s):
NORTH CAROLINA UNIV AT CHAPEL HILL DEPT OF CHEMISTRY
Descriptive Note:
Technical rept.,
Pagination:
0014

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release
Distribution Statement:
Approved For Public Release; Distribution Is Unlimited.

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TR-46
Monitor Series:
OCNR
 Subject Terms
Joint Capability Areas:
JCA_6.3.3_Spectrum Management; JCA_6_Net Centric; JCA_6.3_Net Management; JCA_1.2_Force Preparation; JCA_1_Force Support; JCA_1.2.3_Educating
Communities of Interest:
Advanced Electronics
Descriptor(s):
*MAGNETIC PROPERTIES, *SPECTROSCOPY, *ELECTRICAL CONDUCTIVITY, *IRON, *ORGANIC COMPOUNDS, *NITRATES, *ELECTRICAL PROPERTIES, TEMPERATURE, RESONANCE, WIDTH, MAGNETIC MOMENTS, PARAMAGNETISM, SPIN STATES, ELECTRON TRANSFER, TRANSFER, VALUE, CHARGE TRANSFER, YIELD, SIGNALS, MOMENTS, ROOM TEMPERATURE, ELECTRONS, CONDUCTIVITY
Field(s)/Group(s):
Organic Chemistry, Physical Chemistry, Electricity and Magnetism, Atomic and Molecular Physics and Spectroscopy
Keyword(s):
*TTFV(TETRATHIAFULVALENE), IRON NITRATE
Report Date:
1992 Dec 15