Synthesis and Reactivity of 1-Methyl-e-Ethynylpyridinium Triflate

reportActive / Technical Report | Accession Number: ADA250638 | Open PDF

Abstract:

1-Methyl-4-ethynylpyridinium triflate has been prepared by treatment of 4-ethynylpyridine with methyl triflate in methylene chloride. This new active acetylenic monomer trimerized to tris-1, 3,5-1-methylpyridinium-4-yl benzene triflate when heated in aqueous solution. The new compounds were isolated and characterized.

Author(s):
Zeldin, Martel ; Rubinsztajn, Slawomir ; Fife, Wilmer K.
Author Organization(s):
INDIANA UNIV-PURDUE UNIV AT INDIANAPOLIS DEPT OF CHEMISTRY
Descriptive Note:
Technical rept.,
Supplementary Note:
DOI: 10.21236/ADA250638
Pagination:
0006

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release
Distribution Statement:
Approved For Public Release; Distribution Is Unlimited.

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TR-16
Contract/Grant Number(s):
N00014-91-J-1434
Monitor Series:
ONR
 Subject Terms
Joint Capability Areas:
JCA_1_Force Support; JCA_1.3_Human Capital Management; JCA_1.3.2_Personnel Management; JCA_6.3.3_Spectrum Management; JCA_1.2_Force Preparation; JCA_6_Net Centric; JCA_1.2.3_Educating; JCA_6.3_Net Management; JCA_8_Building Partnerships
Communities of Interest:
No COI(s) Identified
Descriptor(s):
*MONOMERS, SYNTHESIS(CHEMISTRY), CHLORIDES, METHYLENES, ALKYLATION, AROMATIC COMPOUNDS, POLYMERIZATION
Field(s)/Group(s):
Organic Chemistry
Keyword(s):
*POLYACETYLENES, METHYL ETHYNYLPYRIDINIUM TRIFLATE
Report Date:
1992 May 15