Electrochemical Behavior of the Oxide Formed by Reduction of RuO4(2-): A ph-Dependent Ruthenium Oxide-Based Microelectrochemical Transistor

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Abstract:

Reduction of ruthenium tetraoxide ion in alkaline results in deposition of an oxide, RuOx exhibiting characteristics intermediate between redox conducting and electronically conducting materials. Like a conventional redox polymer, RuOx shows a well-defined cyclic voltammetry wave and a conductivity maximum at a potential close to the peak of the wave. Keywords Ruthenium oxide, Microelectrochemical transistors.

Author(s):
Lyons, Donald F. ; Schloh, Martin O. ; Hickman, James J. ; Wrighton, Mark S.
Author Organization(s):
MASSACHUSETTS INST OF TECH CAMBRIDGE DEPT OF CHEMISTRY
Descriptive Note:
Technical rept. no. 37, May 1989-May 1990
Pagination:
0047

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release
Distribution Statement:
Approved For Public Release; Distribution Is Unlimited.

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TR-37
Contract/Grant Number(s):
N00014-84-K-0553
 Subject Terms
Joint Capability Areas:
JCA_6.3.3_Spectrum Management; JCA_6_Net Centric; JCA_1.3_Human Capital Management; JCA_1_Force Support; JCA_1.3.2_Personnel Management; JCA_6.1.3_Switching and Routing; JCA_6.3_Net Management; JCA_6.1_Information Transport; JCA_JCA_4.1.2_Sustain the Force; JCA_4.1_Deployment and Distribution; JCA_1.2.7_Experimentation
Communities of Interest:
Advanced Electronics
Descriptor(s):
*RUTHENIUM COMPOUNDS, *OXIDES, *TRANSISTORS, *ELECTROCHEMISTRY, OXIDATION REDUCTION REACTIONS, ALKALINITY, WAVES, DEPOSITION, CYCLES, POLYMERS, VOLTAMMETRY
Field(s)/Group(s):
Physical Chemistry
Report Date:
1990 May 16