Reduction Pathways of Cyclooctatetraene Iron Tricarbonyl as Examined Using Infrared Spectroelectrochemistry.

reportActive / Technical Report | Accession Number: ADA188778 | Open PDF

Abstract:

The nature of the redox-induced structural changes of cyclooctatetraene iron tricarbonyl are explored using fourier transform infrared spectroelectrochemistry. The results provide a simple demonstration of the detailed mechanistic information that can be obtained by employing FTIR instrumentation along with a thin-layer electrochemical arrangement. Keywords Infrared spectroelectrochemistry, Redox kinetics.

Author(s):
Golovin, M. N. ; Weaver, Michael J.
Author Organization(s):
PURDUE UNIV LAFAYETTE IN DEPT OF CHEMISTRY
Descriptive Note:
Technical rept. 1 Oct 86-30 Sep 87,
Pagination:
0013

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TR-72
Contract/Grant Number(s):
N00014-86-K-0556
 Subject Terms
Joint Capability Areas:
JCA_6.3.3_Spectrum Management; JCA_6_Net Centric; JCA_6.3_Net Management; JCA_1_Force Support; JCA_1.2_Force Preparation; JCA_1.2.3_Educating
Communities of Interest:
No COI(s) Identified
Descriptor(s):
*CYCLOOCTATETRAENE, *INFRARED SPECTROSCOPY, *IRON, *OXIDATION REDUCTION REACTIONS, *METAL CARBONYLS, DEMONSTRATIONS, ELECTROCHEMISTRY, MOLECULAR STRUCTURE, FOURIER SPECTROSCOPY, REACTION KINETICS
Field(s)/Group(s):
Organic Chemistry, Physical Chemistry
Report Date:
1987 Sep 25