Spectroscopic Studies of Lasing Transitions in the Diatomic Mercury Halides.

reportActive / Technical Report | Accession Number: ADA151553 | Open PDF

Abstract:

The B-X, C-X, and D-X emission transitions of HgCl, HgBr and HgI and the B-X transition of XeF have been photographed and analyzed for isotopically pure HgX and XeF molecules. New methods have been devised for fitting data and approximating potential curves for heavy diatomics like these molecules. Results of the analysis for these molecules offer significant improvements in their spectroscopic parameters and related properties, such as potential curves, Franck-Condon factors, dissociation energies and partition functions. Originator-supplied keywords include mercury halides, zenon fluoride, HgCl, HgBr, HgI, XeF, electronic transition lasers, electronic spectroscopy, diatomic spectroscopy, vibrational analysis, rotational analysis, emission spectroscopy, potential curves, Franck-Condon factors, partition functions.

Author(s):
Tellinghuisen, J.
Author Organization(s):
VANDERBILT UNIV NASHVILLE TN DEPT OF CHEMISTRY
Descriptive Note:
Final rept. 1 May 81-30 SEp 84,
Pagination:
0034

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Contract/Grant Number(s):
N00014-81-K-0477
Task Number(s):
RR0110701
Project Number(s):
RR01107
 Subject Terms
Joint Capability Areas:
JCA_5_Command and Control; JCA_5.3_Planning; JCA_1.2.3_Educating
Modernization Areas:
Quantum Science and Computing
Communities of Interest:
Energy and Power Technologies
Descriptor(s):
*SPECTROSCOPY, *LASERS, *HALIDES, *MERCURY, *DIATOMIC MOLECULES, *ELECTRON TRANSITIONS, MOLECULAR VIBRATION, CHLORIDES, MOLECULAR ROTATION, EMISSION SPECTROSCOPY, FLUORIDES, BROMIDES, ELECTRON SPECTROSCOPY, XENON, IODIDES
Field(s)/Group(s):
Radiation and Nuclear Chemistry, Atomic and Molecular Physics and Spectroscopy
Keyword(s):
PE61153N, WUNR395612
Report Date:
1985 Feb 01