Physical Chemistry of Exothermic Gas-Aerosol Calaorimetry.

reportActive / Technical Report | Accession Number: ADA150872 | Open PDF

Abstract:

Infrared emission has been observed from exothermic gas-aerosol reactions. The principal system examined was liquid chlorosulfonic and aerosol reacting with ammonia and water vapor. The aerosols employed in this study have been polydisperse with mass medium diameters of a few microns. In order to develop methods to investigate the kinetics of rapid gas-aerosol reactions, a generator has been designed which produces monodisperse aerosol in the 0.5 - 1.5 micrometer diameter range. This generator can be used with corrosive and reactive liquids. A flow reaction and sizing system has been designed and constructed. Originator supplied keywords include Infrared emission, Gas-aerosol reactions, Exothermic reactions, Acid-base reactions, Chlorosulfonic acid aerosol, Gaseous ammonia.

Author(s):
Mackay, R. A.
Author Organization(s):
DREXEL UNIV PHILADELPHIA PA DEPT OF CHEMISTRY
Descriptive Note:
Contractor rept. Jan 83-Jan 84,
Supplementary Note:
DOI: 10.21236/ADA150872
Pagination:
0045

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
CRDC-CR-84120
Contract/Grant Number(s):
DAAK11-80-C-0051
Project Number(s):
1L162622A552
Monitor Series:
CR-84120
 Subject Terms
Joint Capability Areas:
JCA_5_Command and Control
Modernization Areas:
Microelectronics
Communities of Interest:
Advanced Electronics
Descriptor(s):
*AEROSOLS, *GASES, *EXOTHERMIC REACTIONS, *CALORIMETRY, EMISSION, DISPERSING, REACTION KINETICS, ACID BASE EQUILIBRIUM, AMMONIA, INFRARED RADIATION, CHLORINE, WATER VAPOR, SULFONIC ACIDS, AEROSOL GENERATORS
Field(s)/Group(s):
Physical Chemistry
Keyword(s):
PE62622A, AS552
Report Date:
1985 Jan 01