Conductivities in Thionyl Chloride

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Abstract:

Conductivity measurements in thionyl chloride are reported for dilute solutions of AlCl3, LiAlCl4, and the tetrapropylammonium Pr4N salts Pr4NCl, Pr4NClO4, Pr4NAlCl4. The data for electrolyte solutions having concentrations in the range of approximately 0.01 to 1 x 10 expn -5 mole dm expn -3 were fitted empirically to an equation of the Fuoss-Hsia type. In all cases except for AlCl3 ion pair formation was found to be extensive. AlCl3 solutions in thionyl chloride appear to be complex possibly owing to the formation of complex species such as Al2Cl6 and Al2Cl7-. The effect of ionic strength on the solubility of LiCl is discussed.

Author(s):
Salomon, Mark
Author Organization(s):
ARMY ELECTRONICS TECHNOLOGY AND DEVICES LAB FORT MONMOUTH NJ
Descriptive Note:
Journal article
Supplementary Note:
Published in the Journal of the Electrochemical Society, v128 n2 p233-236, Feb 1981.
Pagination:
0004

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release, Document Partially Illegible
Distribution Statement:
Approved For Public Release; Distribution Is Unlimited. Document Partially Illegible.

RECORD

Collection: TR
Identifying Numbers
Monitor Series:
ETDL
 Subject Terms
Joint Capability Areas:
JCA_5.3_Planning; JCA_5_Command and Control
Modernization Areas:
Microelectronics
Communities of Interest:
Advanced Electronics
Descriptor(s):
*ELECTRICAL CONDUCTIVITY, *ELECTROCHEMISTRY, *MEASUREMENT, *THIONYL CHLORIDE, ALUMINUM COMPOUNDS, CHLORATES, CHLORIDES, ELECTROLYTES, IONS, LITHIUM COMPOUNDS, REPRINTS, SOLUBILITY
Field(s)/Group(s):
Physical Chemistry
Report Date:
1981 Feb 01