On the Lowest Excited Singlet State of Osmium Tetroxide.

reportActive / Technical Report | Accession Number: ADA099278 | Open PDF

Abstract:

Two photon spectra of OsO4 in the region below the first strong one photon transition are observed and analyzed. The data fit a linear Jahn-Teller Txt calculation. An assignment of the two photon features as arising from a T sub 1 electronic state, origin at 27,295cm, with a dominant linear Jahn-Teller active t sub 2 vibration nu sub 3, nu sub 3588cmnu sub 3 1960 cm, and with Jahn-Teller parameter D0.5 is proposed. Based on these findings the two observed one photon states are discussed and qualitatively analyzed in a parallel fashion.

Author(s):
Swift, K. M. ; Bernstein, E. R.
Author Organization(s):
COLORADO STATE UNIV FORT COLLINS DEPT OF CHEMISTRY
Descriptive Note:
Technical rept.,
Pagination:
0034

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TR-3
Contract/Grant Number(s):
N00014-79-C-0647
 Subject Terms
Joint Capability Areas:
JCA_1.2.5_Lessons Learned; JCA_1.2.3_Educating
Modernization Areas:
Microelectronics
Communities of Interest:
Energy and Power Technologies
Descriptor(s):
*TWO PHOTON ABSORPTION, *MOLECULAR ENERGY LEVELS, *TETROXIDES, *OSMIUM COMPOUNDS, EXCITATION, ELECTRONIC STATES, PHOTONS
Field(s)/Group(s):
Quantum Theory and Relativity
Keyword(s):
Jahn Teller parameters, Osmium tetroxide
Report Date:
1981 Mar 10