Chemical Reactivity of Cyanogen Chloride in Aqueous Solution.

Active / Technical Report | Accession Number: ADA090555 |

Abstract:

Studies of the chemical reactivity of cyanogen chloride with various nucleophiles in aqueous solutions were continued. Spectrophotometric techniques, as well as the colorimetric technique described in the previous report, were used for analysis. Nucleophiles investigated were pyridine, piperidine, trimethylamine, -picoline, sec-butylamine, acetaldoxime, and hydriodic acid. A Bronsted plot with all nucleophiles thus far studies is included. Author

Author(s):

Edwards, John O. ; Sauer, Maria

Author Organization(s):

BROWN UNIV PROVIDENCE RI

Descriptive Note:

Quarterly status rept. no. 2, 1 Dec 71-29 Feb 72,

Pagination:

0016

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:

Approved For Public Release

RECORD

Collection: TR

Identifying Numbers

Contract/Grant Number(s):

DAAA15-71-C-0478

Project Number(s):

1W662710A095

Subject Terms

Joint Capability Areas:

JCA_1.2_Force Preparation; JCA_1_Force Support; JCA_1.2.3_Educating; JCA_5.3_Planning; JCA_5_Command and Control; JCA_6_Net Centric

Communities of Interest:

No COI(s) Identified

Descriptor(s):

*AMINES, *CHEMICAL REACTIONS, *CHLORIDES, *CYANOGEN, METHYLAMINE, REACTION KINETICS, SOLUTIONS(MIXTURES), CONSTANTS, BUTYL RADICALS, ABSORPTION SPECTRA, PH FACTOR, PYRIDINES, COLORIMETRY, ALKALINITY, BASES(CHEMISTRY), DISTILLATION, BUFFERS(CHEMISTRY), SPECTROPHOTOMETERS, PIPERIDINES

Field(s)/Group(s):

Atomic and Molecular Physics and Spectroscopy

Keyword(s):

Nucleophiles, Trimethylamine, V Picoline, Acetaldoxime, Hydriodic acid, PE62710A, AS095

Report Date:

1973 Jan 01