Reaction of (Ir(cyclo-octa-1,5-diene)(P(p-tolyl)3)2) (nido-7,8-C2B9H12) with Hydrogen; Synthesis and X-Ray Structure of 3,9-((H)2(P(p-tolyl)3)2Ir)-3,9-Micro-(H)2-7,8-C2B9H10.

reportActive / Technical Report | Accession Number: ADA084837 | Open PDF

Abstract:

This report deals with the treatment of the ion pair IRCODPR32 NIDO-7.8-C2B9H12 with hydrogen and their Nido-metallocarborane products.

Author(s):
Doi, James A. ; Teller, Raymond G. ; Hawthorne, M. Frederick
Author Organization(s):
CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY
Descriptive Note:
Interim rept.,
Pagination:
0021

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TR-109
Contract/Grant Number(s):
N00014-76-C-0390
 Subject Terms
Joint Capability Areas:
JCA_1.2_Force Preparation; JCA_1_Force Support; JCA_1.2.3_Educating; JCA_5_Command and Control; JCA_6_Net Centric
Modernization Areas:
Fully Networked C3
Communities of Interest:
Weapons Technologies
Descriptor(s):
*REACTION KINETICS, *SYNTHESIS(CHEMISTRY), *X RAY DIFFRACTION, *HYDROGEN, *MOLECULAR STRUCTURE, CRYSTAL STRUCTURE, NUCLEAR MAGNETIC RESONANCE, ORGANOMETALLIC COMPOUNDS, ATOMS, CHEMICAL BONDS, CATALYSTS, CYCLOHEXANES, ABSORPTION, INFRARED SPECTRA, ISOMERIZATION, GALLIUM COMPOUNDS, ALKYL RADICALS, METAL COMPLEXES, ALKENES, CARBORANES, CARBORANYL RADICALS, IRIDIUM COMPOUNDS
Field(s)/Group(s):
Organic Chemistry, Atomic and Molecular Physics and Spectroscopy
Keyword(s):
Microanalysis, Metallocarborane complexes, Ligands, Bridging(Chemistry), Nido compounds, Closo compounds, Tolyl compounds, WUNR053608
Report Date:
1980 May 12