The X-Ray Crystal Structure of Trimethyltin (IV) Azide. A Unique One-Dimensional (ch3)3Sn) Delta + (ch3)3Sn(N3)2) Delta-)n Polymer.

Cunningham, Desmond; Hossain, M. B.; Molloy, K. C.; Helm, D. Van Der; Zuckerman, J. J.

The X-Ray Crystal Structure of Trimethyltin (IV) Azide. A Unique One-Dimensional (ch3)3Sn) Delta + (ch3)3Sn(N3)2) Delta-)n Polymer.

Active / Technical Report | Accession Number: ADA075834 |

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Abstract:

Our 1978 review of the tin structural literature reveals many examples of axially-most electronegative, trigonal bipyramidal triorganotin moieties in associated polymer chains, but the structure of trimethyltin azide is unique in consisting of SnC3 moieties in alternating CH3 3 Sndelta cationic and N3CH33SnN3 delta - aniotic environments in a one-dimensional array with the tin atoms bridged at unequal distances by the alpha-nitrogen atoms of the azide group at which site the chains are bent. Author

Author(s):

Cunningham, Desmond ; Hossain, M. B. ; Molloy, K. C. ; Helm, D. Van Der ; Zuckerman, J. J.

Author Organization(s):

OKLAHOMA UNIV NORMAN DEPT OF CHEMISTRY

Descriptive Note:

Technical rept.,

Pagination:

0012

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:

Approved For Public Release

RECORD

Collection: TR

Identifying Numbers

Report Number(s):

TR-12

Contract/Grant Number(s):

N00014-77-C-0432

Subject Terms

Joint Capability Areas:

JCA_1.2.3_Educating

Communities of Interest:

No COI(s) Identified

Descriptor(s):

*COMPLEX COMPOUNDS, *ORGANOMETALLIC COMPOUNDS, *TIN COMPOUNDS, *AZIDES, CRYSTAL STRUCTURE, METHYL RADICALS, POLYMERS, ONE DIMENSIONAL

Field(s)/Group(s):

Polymer Chemistry, Crystallography

Keyword(s):

Trimethyltin azide, WUNR053636

Report Date:

1979 Sep 24