The Reaction of Phenyllithium with Poly-(Dichlorophosphazene).

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Abstract:

The reactions between polydichlorophosphazene, npcl2n, leads to both halogen substitution and chain cleavage. A new series of polymers was prepared when 10 of the chlorine atoms were replaced by phenyl groups and the remaining halogen in then replaced by trifluoroethoxy or butyl -amino groups. Author

Author(s):
Allcock, H. R. ; Chu, C. Ting-wah
Author Organization(s):
PENNSYLVANIA STATE UNIV UNIVERSITY PARK DEPT OF CHEMISTRY
Descriptive Note:
Interim technical rept.,
Pagination:
0028

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TR-7
Contract/Grant Number(s):
N00014-75-C-0685
 Subject Terms
Joint Capability Areas:
JCA_6.3.3_Spectrum Management; JCA_1_Force Support; JCA_6.3_Net Management; JCA_6_Net Centric; JCA_1.2_Force Preparation; JCA_1.2.3_Educating; JCA_5_Command and Control; JCA_5.6.3_Assess Achievement of Objectives; JCA_5.6_Monitor
Communities of Interest:
Ground and Sea Platforms
Descriptor(s):
*POLYMERIZATION, *PHENYL RADICALS, *LITHIUM COMPOUNDS, *PHOSPHAZENE, TEMPERATURE, ORGANOMETALLIC COMPOUNDS, BUTYL RADICALS, SOLVENTS, CHAIN REACTIONS, CHLORINE, CLEAVAGE, SUBSTITUTION REACTIONS, AMMINO COMPOUNDS, HALOGEN COMPOUNDS
Field(s)/Group(s):
Polymer Chemistry, Plastics
Keyword(s):
Phosphazene Trifluoroethoxy, Phosphazene Butylamino, WUNR356577
Report Date:
1979 Mar 08