Metastable Ions in Mass Spectra.

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Abstract:

Briefly described is research on instrumentation and techniques which have been developed to study the unimolecular decompositions of mass-analyzed gaseous organic ions, including those produced by metastable decompositions and collisional activation CA. CA spectra provide a unique new method for the characterization of the molecular structures of ions, independent of their internal energy. This has been applied to a wide variety of organic ions.

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