Electrode Reactions of the Hydrazonium Ion on Platinized Platinum,

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Abstract:

The kinetics of the cathode reaction and the nature of the equilibrium potential of a platinized platinum electrode at 20C were examined in solutions of hydrazine in H3PO4, by equilibrium polarization measurements. It was shown that, with increase in temperature from 20C to 60C, together with the electrochemical oxidation N2H5 and reduction H reactions on Pt, catalytic decomposition of hydrazine begins. A composite scheme of the electrode process on Pt, under test conditions, is presented.

Author(s):
Glazatova, T. N. ; Vitvitskaya, G. V.
Author Organization(s):
ARMY FOREIGN SCIENCE AND TECHNOLOGY CENTER CHARLOTTESVILLE VA
Supplementary Note:
Trans. of Vsesoyuznyi Nauchno-Issledovatelskii Akkumuliatornyi Institut. Sbornik Rabot po Khimicheskim Istochnikam Toka (USSR) n7 p189-193 1972.
Annotation:
Electrode Reactions of the Hydrazonium Ion on Platinized Platinum--Translation.
Pagination:
0011

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
FSTC-HT-23-1001-74
 Subject Terms
Communities of Interest:
Materials and Manufacturing Processes
Descriptor(s):
*HYDRAZINES, *ELECTROCHEMISTRY, *PLATINUM, USSR, CATIONS, TEMPERATURE, REACTION KINETICS, ELECTRODES, CATALYSIS, TRANSLATIONS
Field(s)/Group(s):
Physical Chemistry
Keyword(s):
*Hydrazonium compounds
Report Date:
1974 Aug 26