Electron Acceptor-Electron Donor Interactions. XV and XVI.

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Abstract:

Electron acceptor and electron donor mixtures that display extremely weak or just contact interaction in a number of solvents are examined. The mixtures exhibit simple eutectic phase diagrams and the thermochromic effect is interpreted as a randomized structure in the liquid, whereas the solid is a two-phase aggregate of isolated acceptor and onor crystals. The charge-transfer spectra of solutions of tungsten and molybdenum hexafluorides and iodine heptafluoride in n-hexane and cyclohexane were obtained.

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