REACTIONS OF ALKYLPEROXY AND ALKOXY RADICALS.

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Abstract:

The reactions of small alkylperoxy and alkoxy radicals are reviewed and discussed. These radicals can decompose unimolecularly, though their rate constants are often in the second-order region. They abstract hydrogen atoms from alkanes, aldehydes, esters, and acids, add to olefins, and may react with O2. Furthermore, interactions with other radicals can lead to either disproportionation or combination. Particular attention is given to CH3O2 and CH3O, and a number of rate constants are estimated. Author

Author(s):
Heicklen, Julian
Author Organization(s):
AEROSPACE CORP EL SEGUNDO CA LABS DIV
Descriptive Note:
Rept. for 1 Dec 66-31 Jan 67,
Pagination:
0043

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TR-1001(2250-40)-11, SSD-TR-67-68
Contract/Grant Number(s):
AF 04(695)-1001
Monitor Series:
TR-67-68
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*CHEMICAL REACTIONS, ORGANIC OXYGEN COMPOUNDS), (*REACTION KINETICS, PEROXIDES), PHOTOLYSIS, RECOMBINATION REACTIONS, PHOTOCHEMICAL REACTIONS, PYROLYSIS, CHEMICAL EQUILIBRIUM, HEAT OF ACTIVATION, OXIDATION, DECOMPOSITION
Field(s)/Group(s):
Atomic and Molecular Physics and Spectroscopy
Keyword(s):
ACTIVATION ENERGY, FLASH PHOTOLYSIS, HEAT OF DISSOCIATION, METHOXY RADICALS, PHOTOOXIDATION, CONSTANTS, RATES, UNIMOLECULAR DECOMPOSITION
Report Date:
1967 Mar 01