Transition-Metal and Carborane Derivatives Obtained from B18H22.

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Abstract:

Reaction of n- or i-B18H202- with a variety of phosphine and carbonyl substituted complexes of cobalt, rhodium, nickel, palladium and platinum produced new metal-borane complexes of the general type, B18H20Metalligandn. Cyclohexyl isocyanide reacts with i-B18H22 to form the carborane, B18H20CNH2C6H11. A nonpolar complex B18H20 pyridine2 has been obtained by the reaction of pyridine with n-B18H22. Author

Author(s):
Sneath, Raymond L. ; Todd, Lee J.
Author Organization(s):
INDIANA UNIV BLOOMINGTON DEPT OF CHEMISTRY
Descriptive Note:
Technical rept.,
Pagination:
0033

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TR-8
Contract/Grant Number(s):
N00014-67-A-0289-0003
Project Number(s):
NR-052-495
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
*BORATES, *BORANES, *COMPLEX COMPOUNDS, CHEMICAL REACTIONS, NICKEL COMPOUNDS, PHOSPHINE, NUCLEAR MAGNETIC RESONANCE, INFRARED SPECTRA, SALTS, COBALT COMPOUNDS, RHODIUM COMPOUNDS, PALLADIUM COMPOUNDS, PYRIDINES, MOLECULAR STRUCTURE, PLATINUM COMPOUNDS
Field(s)/Group(s):
Inorganic Chemistry
Keyword(s):
BORON 11 NUCLEAR MAGNETIC RESONANCE, ISOCYANIDES
Report Date:
1972 Jun 01