Fluorine-19 Nuclear Magnetic Resonance

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Abstract:

Several series of diadducts of titanium tetrafluoride were studied with high resolution fluorine-19 nuclear magnetic resonance spectroscopy. These consisted of studies with aromatic amine oxides, amides and sulfoxides as bases. Mixed diadducts of TiF4 with the aromatic amine oxides and tetramethylurea as a reference base were also investigated. Both basicity and steric interactions were found to affect the 19F chemical shifts. Some aromatic amine oxide, amide and sulfoxide adducts with tin tetrafluoride were also investigated. Cis and trans isomers were found for all complexes in which the donor molecule was small. Only second order spectra were found for SnF42D complexes formed with the relatively strong bases.

Author(s):
Ragsdale, Ronald O.
Author Organization(s):
UTAH UNIV SALT LAKE CITY
Descriptive Note:
Technical rept. Mar 1969-Jun 1971
Pagination:
0058

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release
Distribution Statement:
Approved For Public Release; Distribution Is Unlimited.

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
AFML-TR-71-224
Contract/Grant Number(s):
F33615-69-C-1016
Task Number(s):
736702
Project Number(s):
AF-7367
Monitor Series:
TR-71-224, AFML
 Subject Terms
Joint Capability Areas:
JCA_6.3.3_Spectrum Management; JCA_6_Net Centric; JCA_6.3_Net Management; JCA_5_Command and Control; JCA_3.2_Engagement; JCA_3_Force Application; JCA_1_Force Support; JCA_3.2.1_Kinetic Means; JCA_8.2.4_Leverage Capacities and Capabilities of Security Establishments; JCA_8.2_Shape; JCA_8_Building Partnerships; JCA_1.2_Force Preparation; JCA_5.3_Planning; JCA_1.2.3_Educating
Modernization Areas:
Fully Networked C3
Communities of Interest:
C4I
Descriptor(s):
*COMPLEX COMPOUNDS, *NUCLEAR MAGNETIC RESONANCE, *FLUORIDES, SULFOXIDES, AMINES, OXIDES, UREA, TITANIUM COMPOUNDS, MOLECULAR STRUCTURE, AMIDES, MOLECULAR ISOMERISM, TIN COMPOUNDS
Field(s)/Group(s):
Inorganic Chemistry
Keyword(s):
*ADDITION COMPOUNDS, *FLUORINE 19 NUCLEAR MAGNETIC RESONANCE, *TIN FLUORIDES, *TITANIUM(IV) FLUORIDE, CHEMICAL SHIFT(NUCLEAR MAGNETIC RESONANCE)
Report Date:
1971 Dec 01