Applications of Far Infrared Spectroscopy to the Study of the Structure and Dynamics of Organic Molecules-Alcohols.

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Abstract:

The far infrared spectra of a number of alcohols have been recorded as pure samples and as very dilute solutions in cyclohexane. A characteristic band 208 plus or minus 10cm is present in the spectra of aliphatic alcohols dissolved in cyclohexane. On the basis of the deuterium shifts this band is assigned to OH torsion. This characteristic band was quite strong in the spectrum of a 1 solution of chlesterol in cyclohexane. The position of this band is nearly independent of steric effects but is very sensitive to electrostatic interactions. The literature concerned with group frequencies and rotational conformers of alcohols is discussed. Author

Author(s):
Craven, Stephen M.
Author Organization(s):
MIAMI UNIV OXFORD OHIO DEPT OF CHEMISTRY
Descriptive Note:
Technical rept. Oct 70-May 71,
Pagination:
0066

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
AFML-TR-71-192
Contract/Grant Number(s):
F33615-70-C-1021
Task Number(s):
736005
Project Number(s):
AF-7360
Monitor Series:
TR-71-192
 Subject Terms
Joint Capability Areas:
JCA_6.3.3_Spectrum Management; JCA_6.3_Net Management; JCA_6_Net Centric
Communities of Interest:
No COI(s) Identified
Descriptor(s):
*ALCOHOLS, *INFRARED SPECTRA, SOLUTIONS(MIXTURES), MOLECULAR ISOMERISM, MOLECULAR STRUCTURE, PROPANOLS, CHOLESTEROL, ETHANOLS
Field(s)/Group(s):
Atomic and Molecular Physics and Spectroscopy
Keyword(s):
MOLECULAR CONFORMATION, *FAR INFRARED SPECTROSCOPY
Report Date:
1971 Sep 01