Acid-Base Equilibria and Titrations and Electrochemical Equilibria in Acetonitrile.

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Abstract:

Very briefly discussed are studies which have been made of acid-base equilibria and titrations and also of conjugation in acetonitrile AN as a solvent. Dissociation constants of a host of uncharged and cationic acids have been determined, including acid-base indicators. The protonation constants of water, methanol, butanol and diethylether in AN have been determined. The heteroconjugation constants of sulfate and bisulfate ions in AN with uncharged hydrogen bond donors have been determined. Author

Author(s):
Koltoff, I. M.
Author Organization(s):
MINNESOTA UNIV MINNEAPOLIS DEPT OF CHEMISTRY
Descriptive Note:
Final scientific rept. 1 Oct 66-28 Feb 71,
Pagination:
0007

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
AFOSR-TR-71-0678
Contract/Grant Number(s):
AF-AFOSR-1223-67
Project Number(s):
AF-9536
Monitor Series:
TR-71-0678
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*ACETONITRILE, *ACID BASE EQUILIBRIUM), (*ORGANIC SOLVENTS, ACETONITRILE), ELECTROCHEMISTRY, MOLECULAR ASSOCIATION, COMPLEX COMPOUNDS
Field(s)/Group(s):
Atomic and Molecular Physics and Spectroscopy
Keyword(s):
HYDROGEN BONDING
Report Date:
1971 Mar 01