Production of H3O(+).nH2O From NO(+) Precursor in NO-H2O Gas Mixtures,

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Abstract:

Stationary afterglow techniques were employed to determine reaction rate constants for ions reacting in NO-H2O gas mixtures. Krypton resonance radiation at 123.6 and 116.5 nm is used to ionize only the NO molecules. The NO ion is the precursor to a chain of reactions which result in NO.nNO n1,2, NO.nH2O n1,2,3, and H3O.nH2O n2,3,4 being formed. Rate constants andor equilibrium constants are provided for all forward and all reverse reactions at 296 K. Author

Author(s):
Puckett, Lawrence J. ; Teague, Marion W.
Author Organization(s):
BALLISTIC RESEARCH LABS ABERDEEN PROVING GROUND MD
Pagination:
0039

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
BRL-1516
Task Number(s):
1T061102B53A15
Project Number(s):
RDT/E-1-T-061102-B-53-A, DASA-NWER-HD-010
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*IONOSPHERE, CHEMICAL REACTIONS), (*NITROGEN OXIDES, *PHOTOCHEMICAL REACTIONS), (*AFTERGLOWS, NITROGEN OXIDES), (*WATER, IONOSPHERE), IONS, REACTION KINETICS, HYDRATES, CHEMICAL EQUILIBRIUM, WATER VAPOR
Field(s)/Group(s):
Atmospheric Physics, Radiation and Nuclear Chemistry
Keyword(s):
*NITROGEN OXIDE(NO), CHEMICAL REACTION MECHANISMS, PHOTOCHEMICAL REACTIONS, *ION MOLECULE INTERACTIONS, D REGION
Report Date:
1970 Dec 01