Mass Special Study of the Decomposition of Chlorine Fluoride Behind Shock Waves.

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Abstract:

The thermal decomposition of chlorine fluoride has been studied over the temperature range 2000-2950K using the technique of mass spectral sampling behind reflected shock waves. The reaction has been found to be complex, and evidence is offered to support the suggested mechanism which consists of the reactions ClF M to Cl F M, Cl ClF Cl2 F, Cl2 M to 2Cl M. From experimental data k-2 is estimated to be 1 x 10 to the 12th ccmole sec. Author

Author(s):
Mcintyre, James A. ; Diesen, Ronald W.
Author Organization(s):
DOW CHEMICAL CO MIDLAND MICH CHEMICAL PHYSICS RESEARCH LAB
Descriptive Note:
Technical rept.,
Pagination:
0018

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
SL-210077
Contract/Grant Number(s):
Nonr-3814(00)
Project Number(s):
NR-092-514
 Subject Terms
Joint Capability Areas:
JCA_3.2_Engagement; JCA_3_Force Application; JCA_3.2.1_Kinetic Means
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*CHLORINE COMPOUNDS, *DECOMPOSITION), SHOCK WAVES, FLUORIDES, REACTION KINETICS, MASS SPECTROSCOPY
Field(s)/Group(s):
Inorganic Chemistry, Atomic and Molecular Physics and Spectroscopy
Keyword(s):
CHLORINE MONOFLUORIDE, *CHLORINE FLUORIDES
Report Date:
1970 Oct 15