THE CHEMISTRY OF BIS(pi-(3)-1,2-DICARBOLLYL) METALATES. PROTONATION AND B-SUBSTITUTION.

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Abstract:

The sandwich bonded bispi-3-1,3-dicarbollylFeII-2 ion is protonated in strongly acidic media to form what may prove to be the analog of protonated ferrocene. This species readily reacts with dialkyl-sulfides to form B-substituted bisdicarbollylironII and -III species. Analogous reactions have been carried out employing bisdicarbollyliron III and -cobaltIII anions. The preparation, characterization and structures of these complexes are discussed. Author

Author(s):
Hawthorne, M. Frederick ; Warren, Leslie F., Jr. ; Callahan, Kenneth P. ; Travers, Neill F.
Author Organization(s):
CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY
Descriptive Note:
Technical rept.,
Pagination:
0039

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TR-25
Contract/Grant Number(s):
N00014-69-A-0200-4019
Project Number(s):
NR-053-481
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*BORATES, *COMPLEX COMPOUNDS), (*IRON COMPOUNDS, COMPLEX COMPOUNDS), SYNTHESIS(CHEMISTRY), IONS, MOLECULAR STRUCTURE, COBALT COMPOUNDS, NUCLEAR MAGNETIC RESONANCE
Field(s)/Group(s):
Inorganic Chemistry
Keyword(s):
BORON 11 NUCLEAR MAGNETIC RESONANCE, *PROTONATION, DICARBA CLOSO DODECABORANYL METAL COMPLEXES
Report Date:
1970 Sep 14