THE INFRARED SPECTRA OF METHOXYAMINE AND METHOXYAMMONIUM ION.

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Abstract:

The infrared spectra of CH3ONH2, CH3OND2, CH3ONH3Cl- and CH3OND3Cl- were obtained in the region 4000 - 40CM5 WITH THE SAMPLES IN THE FORM OF THIN CRYSTALLINE FILMS AT LIQUID NITROGEN TEMPERATURE. With the exception of the CH3 and NH3 torsions all the fundamentals for methoxyamine and methoxyammonium ion have been observed and assigned. Davies and Spiers assignments for CH3ONH2 have been revised in part and the NH2 twist and wag located. The assignments for CH3ONH3 ion are readily correlated with those for CH3ONH2 and for both species the assignments for the A vibrations are consistent with the product rule. Author

Author(s):
Nelson, H. M.
Author Organization(s):
AIR FORCE ROCKET PROPULSION LAB EDWARDS AFB CALIF
Descriptive Note:
Technical rept. Aug 68-Oct 69,
Pagination:
0034

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
AFRPL-TR-70-3
Project Number(s):
AF-314801ACL
 Subject Terms
Joint Capability Areas:
JCA_6.3.3_Spectrum Management
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*AMINES, *INFRARED SPECTRA), (*AMMONIUM COMPOUNDS, INFRARED SPECTRA), DEUTERIUM COMPOUNDS
Field(s)/Group(s):
Atomic and Molecular Physics and Spectroscopy
Keyword(s):
*METHOXYAMINE
Report Date:
1970 May 01