A SPECTROSCOPIC STUDY OF FERROCENE AND RELATED COMPOUNDS.

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Abstract:

The work discussed in the report is involved with an attempt to explain discrepancies between an earlier vibrational assignment and recent studies of ferrocene, and its derivatives. Low temperature infrared and Raman work has been carried out showing some new and interesting features. The Raman study of a single crystal of ferrocene showed useful polarization features and is used to compare and contrast the original assignment with its alternatives. The infrared spectrum of the solid shows definite evidence for a breakdown in the selection rules. Factor group splitting is of the order of 2cm. Force field calculations and the preparation and spectra of any related compounds considered to be appropriate are also discussed herein. Author

Author(s):
Hyams, Ivan J.
Author Organization(s):
BOWDOIN COLL BRUNSWICK MAINE
Descriptive Note:
Final rept. Jan-Nov 69,
Pagination:
0062

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
AFML-TR-69-321
Contract/Grant Number(s):
F33615-69-C-1247
Task Number(s):
736702
Project Number(s):
AF-7367
Monitor Series:
TR-69-321
 Subject Terms
Joint Capability Areas:
JCA_6.3.3_Spectrum Management
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*FERROCENES, *INFRARED SPECTRA), (*RAMAN SPECTROSCOPY, FERROCENES), FERRATES, POLARIZATION, SINGLE CRYSTALS, SALTS
Field(s)/Group(s):
Atomic and Molecular Physics and Spectroscopy
Keyword(s):
CYCLOPENTADIENYL METAL COMPLEXES
Report Date:
1970 Mar 01