MONOCARBON CARBORANES. IV. POLYHEDRAL ARSA- AND STIBACARBADODECABORANE (11) DERIVATIVES AND RELATED 11-ATOM CAGE FRAGMENTS.

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Abstract:

The syntheses of 1,2-, 1,7-, and 1,12-B10H10CHAs as well as 1,2-, and 1,7-B10H10CHSb are discussed. The conversions of the appropriate icosahedral derivative to 7,8-, or 7,9-B9H10CHAs-, 7,9-B9H10CHAsCH3 or 7,8-B9H10CHSb- are described. The synthesis and X-ray diffraction study of C5H5Co1,2-B9H9CHAs confirm the relative position of the carbon and arsenic atoms in the 1,2-arsa-carboranes and show the distorted nature of these derivatives. Dipole moment and nmr data are presented which aid in elucidating the role of the group V atom in these molecules. Author

Author(s):
Todd, Lee J. ; Burke, Aaron R. ; Garber, Albert R. ; Silverstein, Howard T. ; Storhoff, Bruce N.
Author Organization(s):
INDIANA UNIV BLOOMINGTON DEPT OF CHEMISTRY
Descriptive Note:
Technical rept.,
Pagination:
0033

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TR-3
Contract/Grant Number(s):
N00014-67-A-0289-0003
Project Number(s):
NR-052-495
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*BORON COMPOUNDS, SYNTHESIS(CHEMISTRY)), NUCLEAR MAGNETIC RESONANCE, DIPOLE MOMENTS, ARSENIC COMPOUNDS, ANTIMONY COMPOUNDS, MASS SPECTROSCOPY
Field(s)/Group(s):
Inorganic Chemistry
Keyword(s):
BORON 11 NUCLEAR MAGNETIC RESONANCE
Report Date:
1970 May 01