CERTAIN REGULARITIES OF THE CATALYTIC HYDROGENATION OF NITROBENZENE DERIVATIVES ON RANEY NICKEL,

Finkelshtein, A. V.; Kuzmina, Z. M.

CERTAIN REGULARITIES OF THE CATALYTIC HYDROGENATION OF NITROBENZENE DERIVATIVES ON RANEY NICKEL,

Active / Technical Report | Accession Number: AD0706174 |

Abstract:

Nitrobenzene, m-nitrotoluene, p-nitrotoluene, p-nitrophenol, o-nitrophenol, o-nitroaniline, and p-nitrophenetole were hydrogenated at 20 degrees at hydrogen pressure of 750 mm Hg with Raney nickel used as the catalyst. Kinetic curves and rate constants of the process were taken, and a relationship between the rate constant and the solvate chromic effect was demonstrated. It is stated that the results provide dome confirmation of the assumed presence of a connection between the change in the energy of reaction of molecules of a dissolved substance with the medium and the change in the activation energy of certain reactions.

Author(s):

Finkelshtein, A. V. ; Kuzmina, Z. M.

Author Organization(s):

FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OHIO

Supplementary Note:

Edited trans. of Sibirskii Tekhnologicheskii Institut, Krasnoyarsk. Trudy (USSR) n38 p62-67 1966, by D. Koolbeck.

Annotation:

Certain regularities of the catalytic hydrogenation of nitrobenzene derivatives on raney nickel--Translation.

Pagination:

0010

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:

Approved For Public Release

RECORD

Collection: TR

Identifying Numbers

Report Number(s):

FTD-HT-23-609-69

Project Number(s):

FTD-7230172

Subject Terms

Joint Capability Areas:

JCA_3.2_Engagement; JCA_3_Force Application; JCA_3.2.1_Kinetic Means

Communities of Interest:

Materials and Manufacturing Processes

Descriptor(s):

(*NITROBENZENES, *HYDROGENATION), (*CATALYSTS, HYDROGENATION), (*NITROPHENOLS, HYDROGENATION), NICKEL, REDUCTION(CHEMISTRY), USSR

Field(s)/Group(s):

Physical Chemistry

Keyword(s):

TRANSLATIONS

Report Date:

1970 Jan 21