HYDROGENATION OF BENZENE AND CERTAIN OF ITS DERIVATIVES ON THE RHODIUM-PLATINUM ALLOY CATALYST IN THE LIQUID PHASE,

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Abstract:

A study was made of the effect of various hydrocarbon side groups on the hydrogenation of benzene. According to their hydrogenation speed, the studied compounds appear in the following order benzene ethyl-benzene toluene n-xylene m-xylene o-xylene. The order of reaction, according to substance being hydrogenated, for benzene and o-xylene, is a zero order for the remaining investigated compounds it is close to zeroth order. For the first time it has been shown that the hydrogenation of benzene and its homologues takes place with insignificant displacement of potential. The small displacement of potential makes it possible to assume that the adsorption takes place on the catalyst, the surface of which is occupied by hydrogen. The alcohol displaces aromatic hydrocarbons from the surface of the catalyst, and the reaction does not take place. Author

Author(s):
Sokolskii, D. V. ; Zabotina, A. P.
Author Organization(s):
INSTITUTE OF MODERN LANGUAGES INC WASHINGTON D C TRANSLATION AND INTERPRETATION DIV
Supplementary Note:
Trans. from Izvestiya Vysshikh Uchebnykh Zavedenii. Khimiya i Khimicheskaya Tekhnologiya (USSR) v11 n1 1968.
Annotation:
Hydrogenation of benzene and certain of its derivatives on the rhodium-platinum alloy catalyst in the liquid phase--Translation.
Pagination:
0011

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
USAMERDC-T-1968-69
Contract/Grant Number(s):
DAAK02-68-C-0396
Monitor Series:
T-1968-69
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*BENZENE, *HYDROGENATION), (*XYLENES, HYDROGENATION), (*TOLUENES, HYDROGENATION), REACTION KINETICS, CATALYSTS, PLATINUM ALLOYS, SURFACE PROPERTIES, RHODIUM ALLOYS, USSR
Field(s)/Group(s):
Organic Chemistry
Keyword(s):
SURFACE CHEMISTRY, TRANSLATIONS
Report Date:
1969 Dec 01