IONIC FLUORINE CHEMISTRY.

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Abstract:

The report describes attempts to prepare iodine-fluorine interhalogen salts wherein both ions contain iodine and fluorine, or iodine, fluorine, andor oxygen. Three starting materials were successfully prepared, CsIF6, IF4SbF6, and IF6SbF6, whose metathetical interactions would have given desired interhalogen salts. Failure to find suitable solvents for the intended reactions was primarily responsible for a lack of success in this area. In the course of preparing CsIF6 a previously unreported adduct was isolated, CsIF6.2IF5, and infrared and X-ray characteristics are given. One other positive aspect of the investigations is the partial clarification of the reactions of I2O5 with IF5 and IF7 as regards the synthesis of IO2F and IOF3. Author

Author(s):
Hyde, Gene A. ; Trotz, Samuel I.
Author Organization(s):
OLIN CORP NEW HAVEN CONN CHEMICALS GROUP
Descriptive Note:
Semiannual status rept. no. 5 (Final), 1 May-31 Aug 69,
Pagination:
0034

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Contract/Grant Number(s):
N00014-67-C-0435
Project Number(s):
RR-001-06-02, NR-093-048
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*FLUORIDES, SYNTHESIS(CHEMISTRY)), (*IODINE COMPOUNDS, *COMPLEX COMPOUNDS), (*ANTIMONY COMPOUNDS, COMPLEX COMPOUNDS), CESIUM COMPOUNDS, SALTS, INFRARED SPECTRA, X RAY DIFFRACTION, OXIDES
Field(s)/Group(s):
Inorganic Chemistry
Keyword(s):
*ANTIMONY HALOGEN COMPLEXES, CESIUM HALOGEN COMPLEXES, FLUORO MOLECULAR IONS, FLUOROMOLECULAR IONS, INTERHALOGEN COMPLEXES, IODO MOLECULAR IONS, IODOMOLECULAR IONS, *ION MOLECULE CHEMISTRY, MOLECULAR IONS, OXYHALIDE IONS
Report Date:
1969 Oct 31