CHEMISTRY OF STRAINED OLEFINS.

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Abstract:

Final report on studies concerned with the experimental tests of theory in bond breaking reactions of strained ring compounds. The first test of orbital symmetry control of a thermal 1,3-sigmatropic rearrangement was established. Preliminary work was carried out on the construction of a test in the 1,5-sigmatropic case. New synthetic approaches have been developed to the optically active cycloheptatrienes needed for stereochemical experiments. Author

Author(s):
Berson, Jerome A.
Author Organization(s):
WISCONSIN UNIV MADISON DEPT OF CHEMISTRY
Descriptive Note:
Final rept. 1 Oct 65-30 Sep 69,
Pagination:
0009

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
AFOSR-69-2873TR
Contract/Grant Number(s):
AF-AFOSR-1006-66, AF-AFOSR-1358-68
Project Number(s):
AF-9762
Monitor Series:
69-2873TR
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*CYCLOALKENES, CHEMICAL REACTIONS), MOLECULAR ISOMERISM, CYCLOPROPANES, PYRIMIDINES
Field(s)/Group(s):
Organic Chemistry
Keyword(s):
AZO COMPOUNDS, CYCLOHEPTATRIENE COMPOUNDS, *REARRANGEMENT REACTIONS, SIGMATROPIC REARRANGEMENT REACTIONS
Report Date:
1969 Jun 01