MAGNETIC AND OPTICAL STUDIES OF CUBIC SINGLE CRYSTALS CONTAINING 4d AND 5d IONS.

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Abstract:

The optical spectra of Os4 and Ru4 in single cubic crystals of K2PtCl6 and Cs2ZrCl6 at 4.2 degrees K is reported. The results are analysed in terms of a complete d4 intermediate coupling scheme. Magnetic susceptibilities were calculated and the magnetic moments for all excited states were calculated. A report on a calculation of the intensities for these materials is included. Tables of wavefunctions and magnetic moments for the d4 system are given. Author

Author(s):
Dorain, Paul B.
Author Organization(s):
BRANDEIS UNIV WALTHAM MASS
Descriptive Note:
Final technical rept. 1 Jun 66-1 Jun 69,
Pagination:
0167

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
ARL-69-0088
Contract/Grant Number(s):
AF 33(615)-5228
Project Number(s):
AF-7885
Monitor Series:
69-0088
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*TRANSITION METALS, *INFRARED SPECTRA), (*OSMIUM COMPOUNDS, INFRARED SPECTRA), (*RUTHENIUM COMPOUNDS, INFRARED SPECTRA), COMPLEX COMPOUNDS, SINGLE CRYSTALS, ATOMIC ENERGY LEVELS, MAGNETIC MOMENTS, WAVE FUNCTIONS, CHLORIDES, CESIUM COMPOUNDS, PLATINUM COMPOUNDS, POTASSIUM COMPOUNDS, ZIRCONIUM COMPOUNDS, CRYOGENICS
Field(s)/Group(s):
Atomic and Molecular Physics and Spectroscopy, Solid State Physics
Keyword(s):
*CUBIC CRYSTALS, *D ELECTRONS, *IONIC CRYSTALS, MAGNETIC SUSCEPTIBILITY, VIBRATIONAL ENERGY LEVELS, ZIRCONIUM COMPLEXES
Report Date:
1969 Jun 01