PHOTOCHEMICAL GENERATION OF DIVALENT CARBON DERIVATIVES.

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Abstract:

A brief review of the authors research is presented. Part of the investigation studied the chemical response to ultraviolet radiation of several small ring heterocyclic systems. The phototransformations of beta, gamma-epoxy ketones, dibenzoylstilbene episulfides, arylaroylazetidines, cyclopentyl phenyl ketone, and alpha-diazoacetophenone were examined in mechanistic detail. Photosensitization, quenching, and emission studies were performed in order to describe the excited states involved in these photoreactions as well as to provide for a better understanding of the mechanism of these transformations. Author

Author(s):
Padwa, Albert
Author Organization(s):
STATE UNIV OF NEW YORK BUFFALO DEPT OF CHEMISTRY
Descriptive Note:
Final rept. 1 Feb 65-31 Aug 69,
Pagination:
0008

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
AFOSR-69-2372TR
Contract/Grant Number(s):
AF-AFOSR-820-65, AF-AFOSR-1213-67
Project Number(s):
AF-9762
Monitor Series:
69-2372TR
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*PHOTOLYSIS, *HETEROCYCLIC COMPOUNDS), OXYGEN HETEROCYCLIC COMPOUNDS, NITROGEN HETEROCYCLIC COMPOUNDS, SULFUR HETEROCYCLIC COMPOUNDS, KETONES, SULFIDES
Field(s)/Group(s):
Radiation and Nuclear Chemistry
Keyword(s):
CARBENE IONS, *EPOXY COMPOUNDS, *PHOTOCHEMICAL REACTIONS, PHOTOCHEMICAL REARRANGEMENTS
Report Date:
1969 Sep 19