STRUCTURE OF FRIEDEL-CRAFTS INTERMEDIATES.

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Abstract:

The acetyl chloride-aluminum chloride complex is shown to be normal Lewis acid-carbonyl complex with coordination through the oxygen. Infrared bands previously ascribed to CH3CO in this system are most likely due to decomposition or reaction products. Author

Author(s):
Shirk, James S. ; Wood, J. L.
Author Organization(s):
MONSANTO RESEARCH CORP DAYTON OHIO
Descriptive Note:
Final rept. Sep 66-Aug 67,
Supplementary Note:
Prepared in cooperation with Imperial Coll. of Science and Technology, London (England).
Pagination:
0029

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
AFML-TR-68-272
Contract/Grant Number(s):
F33615-67-C-1363
Task Number(s):
736005
Project Number(s):
AF-7360
Monitor Series:
TR-68-272
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*FRIEDEL CRAFTS REACTIONS, *MOLECULAR STRUCTURE), (*COMPLEX COMPOUNDS, FRIEDEL CRAFTS REACTIONS), (*ALUMINUM COMPOUNDS, FRIEDEL CRAFTS REACTIONS), CHLORIDES, INFRARED SPECTRA, ACETIC ACID, BENZOIC ACIDS, KETONES
Field(s)/Group(s):
Organic Chemistry
Keyword(s):
BENZOYL CHLORIDE COMPLEXES, CARBONYL COMPLEXES, LEWIS ACIDS
Report Date:
1969 Feb 01