ON THE ESTERS OF ETHYLENE-GLYCOL-ARSENOUS ACID

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Abstract:

It was established that by reacting ethylene glycol with arsenic trichloride in an absolute ether medium in the presence of pyridine, the chloroanhydride of ethylene-glycol-arsenous-acid and the full ethylene glycol ester of arsenous acid may be obtained. A simple and convenient method was worked out for producing the ethylene-glycol ester of arsenous acid by way of the reaction of ethylene glycol with arsenous oxide. The bromination of the ethylene-glycol ester of arsenous acid was studied. By this reaction, the bromoanhydride, with structure -CH2OAsBr22, and diethylene-glycol-arsenous acid were isolated. Cyclic mixed esters were synthetized, and their properties and reactions described.

Author(s):
Kamai, Gilm ; Khisamova, Z. L.
Author Organization(s):
ARMY BIOLOGICAL LABS FREDERICK MD
Descriptive Note:
Journal article
Supplementary Note:
Trans. of Zhurnal Obshchei Khimii (USSR) v23 n8 p1323-1330 1953.
Annotation:
On the esters of ethylene-glycol-arsenous acid--Translation.
Pagination:
0012

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release, Document Partially Illegible
Distribution Statement:
Availability: Document Partially Illegible.

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
ABL-TRANS-363
Monitor Series:
ABL/MD
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
*GLYCOLS, *ARSENIC COMPOUNDS, USSR, SYNTHESIS(CHEMISTRY), ANHYDRIDES, CHEMICAL REACTIONS, CHLORIDES, TRANSLATIONS, ESTERS, CHLORINE COMPOUNDS, BROMINATION, OXYGEN HETEROCYCLIC COMPOUNDS
Field(s)/Group(s):
Organic Chemistry
Keyword(s):
ARSENIC ORGANIC COMPOUNDS, ARSENIC(III) CHLORIDE, ARSENIC(III) OXIDE, ETHYLENE GLYCOL, FOREIGN REPORTS
Report Date:
1954 Mar 26