STUDIES IN IVTH GROUP ORGANOMETALLIC CHEMISTRY. VI.  PREPARATION AND POLYMERIZATION OF IVTH GROUP ORGANOMETALLIC DERIVATIVES OF STYRENE AND METHYLSTYRENE.

Noltes, J. G.; Budding, H. A.; Van Der Kerk, G. J. M.

STUDIES IN IVTH GROUP ORGANOMETALLIC CHEMISTRY. VI. PREPARATION AND POLYMERIZATION OF IVTH GROUP ORGANOMETALLIC DERIVATIVES OF STYRENE AND METHYLSTYRENE.

Active / Technical Report | Accession Number: AD0640552 |

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Abstract:

The preparation of a series of IVth group organometallic vinyl monomers derived from styrene and a-methylstyrene, respectively, is described. Thermal or radical-initiated polymerization of the styrene derivatives yielded transparent, solid organometal-substituted polystyrenes. The monomers of the general structure p-CH33MIV-C6H4-CH-CH2 display appreciably different rates of radical-initiated polymerization, i.e. in the order Pb Si C Ge Sn. Author

Author(s):

Noltes, J. G. ; Budding, H. A. ; Van Der Kerk, G. J. M.

Author Organization(s):

INSTITUTE FOR ORGANIC CHEMISTRY TNO UTRECHT (NETHERLANDS)

Descriptive Note:

Technical note,

Supplementary Note:

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:

Approved For Public Release

RECORD

Collection: TR

Identifying Numbers

Report Number(s):

TN-2

Contract/Grant Number(s):

AF 61(052)-218

Subject Terms

Communities of Interest:

No COI(s) Identified

Descriptor(s):

*POLYMERS, *ORGANOMETALLIC COMPOUNDS, *STYRENES, CHEMICAL PROPERTIES, SILANES, GERMANIUM COMPOUNDS, TIN COMPOUNDS, LEAD COMPOUNDS, SYNTHESIS(CHEMISTRY), POLYMERIZATION, CATALYSIS, STYRENE PLASTICS, NETHERLANDS

Field(s)/Group(s):

Polymer Chemistry

Keyword(s):

GERMANIUM ORGANIC COMPOUNDS, GERMANIUM HYDRIDES, LEAD ORGANIC COMPOUNDS, METALORGANIC POLYMERS, METHYL STYRENES, TIN ORGANIC COMPOUNDS

Report Date:

1960 Apr 29