STUDIES IN IVTH GROUP ORGANOMETALLIC CHEMISTRY. XVI. SYNTHESIS OF ORGANOGERMANIUM COMPOUNDS CONTAINING THE P-PHENYLENE GROUP. SOME INFRARED CHARACTERISTICS OF P-PHENYLENE DERIVATIVES OF SILICON, GERMANIUM, TIN AND LEAD.

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Abstract:

A few oligomeric and polymeric p-phenylenegermanes have been prepared by Wurtz-type condensation reactions from p-chlorophenyl and chloro-germanes. The oligomerio and polymeric products obtained have been characterized by infrared spectroscopy, elementary analysis and molecular weight determinations. Infrared spectra in the rocksalt region of phenyl and p-phenylene derivatives of silicon, germanium, tin and lead are discussed. The spectra of the p-phenylene compounds show some characteristic absorption bands shifting to lower frequencies as the weight of the metal atoms in the molecule increases. Author

Author(s):
Leusink, A. J. ; Noltes, J. G. ; Budding, H. A. ; Van Der Kerk, G. J. M.
Author Organization(s):
INSTITUTE FOR ORGANIC CHEMISTRY TNO UTRECHT (NETHERLANDS)
Descriptive Note:
Technical note,
Supplementary Note:
See also AD-640 549.
Pagination:
0021

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TN-8
Contract/Grant Number(s):
AF 61(052)-218
 Subject Terms
Joint Capability Areas:
JCA_6.3.3_Spectrum Management
Communities of Interest:
Advanced Electronics
Descriptor(s):
*ORGANOMETALLIC COMPOUNDS, POLYMERS, GERMANIUM COMPOUNDS, POLYMERIZATION, CONDENSATION REACTIONS, CHLORINE COMPOUNDS, INFRARED SPECTRA, CHEMICAL ANALYSIS, MOLECULAR WEIGHT, SILANES, TIN COMPOUNDS, LEAD COMPOUNDS, BAND SPECTRA, NETHERLANDS
Field(s)/Group(s):
Polymer Chemistry
Keyword(s):
GERMANIUM ORGANIC COMPOUNDS, GERMANIUM HYDRIDES, GERMANIUM ORGANIC COMPLEXES, LEAD ORGANIC COMPOUNDS, SILICON ORGANIC COMPOUNDS, TIN ORGANIC COMPOUNDS, WURTZ SYNTHESIS
Report Date:
1964 Mar 20