EFFECT OF A FERROCENYL SUBSTITUTE ON THE FUNCTIONAL GROUPS IN THE BENZENE RING,

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Abstract:

The dissociation constants K-a and K-b were obtained for several ferrocenyl substituted benzoids and were compared with these constants for amino and hydroxy substituted benzoids. The K-b of p-Ferrocenylaniline is 3 times greater than that of aniline, and 17 times greater than that of p-aminodiphenyl xenylamine the K-b of m-ferrocenylanaline is 23 as great as the p- isomer. Similar results were obtained by the comparison of ferrocenylamine and ferrocenylphenol with phenol and p-hydroxydiphenyl p-phenylphenol, indicating that the ferrocenyl group introduced into the benzene ring behaves as a distinctly expressed substitute of the first order.

Author(s):
Nesmeyanov, A. N. ; Perevalova, E. G. ; Golovnya, R. V.
Author Organization(s):
FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OHIO
Supplementary Note:
Vliyanie Ferrotsenilnogo Zamestitelya na Funktsionalnye Gruppy v Benzolnom Yadre, trans. of Akademiya Nauk SSSR, Doklady, v103 n1 p81-2 1955.
Annotation:
Translation of Russian research: Effect of a ferrocenyl substitute on the functional groups in the benzene ring.
Pagination:
0004

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
F-TS-10072/III ATIC-298672, TT-65-64559
Monitor Series:
65-64559
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
*BENZENE, DISSOCIATION, FERROCENES, ACID BASE EQUILIBRIUM, PH FACTOR, PHENOLS, AMINES, SUBSTITUTION REACTIONS, BASES(CHEMISTRY), USSR
Field(s)/Group(s):
Organic Chemistry
Keyword(s):
FERROCENYL AMINES
Report Date:
1964 Jan 01