ON THE CRYSTAL STRUCTURE OF THE GOLD-RICH PHASES IN THE SYSTEM GALLIUM-GOLD AND RUBIDIUMGOLD (UBER DIE KRISTALLSTRUKTUREN DER GOLDREICHSTEN PHASEN IN DEN SYSTEMEN KALIUM-GOLD UND RUBIDIUM-GOLD),
Abstract:
The crystal structure of the compounds KAu5 and RbAu5 were determined. Both compounds have the hexagonal CaCu5 type structure, space group D1 - P6mmm with one formula weight in the unit cell. The lattice constants 6h for KAu5 are a 5.659 A, c4.483 A and for RbAu5 a 5,760 A, c 4.448 A. Contrary to former statements the formulae of these compounds are KAu5 and RbAu5 and not KAu4 and RbAu4. Author
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