PREPARATION AND PROPERTIES OF BISTRIFLUOROMETHYLSULFURYL PEROXIDE AND TRIFLUOROMETHYL TRIFLUOROMETHANE SULFONATE

reportActive / Technical Report | Accession Number: AD0613524 | Open PDF

Abstract:

Electrolysis of trifluoromethanesulfonic acid at -23C yields the unstable compound bistrifluoromethylsulfuryl peroxide which decomposes explosively to perfluoroethane, sulfur trioxide, and the ester, trifluoromethyl trifluoromethanesulfonate.

Author(s):
Noftle, Ronald E. ; Cady, George H.
Author Organization(s):
WASHINGTON UNIV SEATTLE
Supplementary Note:
DOI: 10.21236/AD0613524
Pagination:
0014

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release
Distribution Statement:
Approved For Public Release; Distribution Is Unlimited.

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
TR-51
Contract/Grant Number(s):
NONR-477-16, ARPA ORDER-26-60
Task Number(s):
2
Monitor Series:
ONR, DARPA
 Subject Terms
Joint Capability Areas:
JCA_6.3.3_Spectrum Management; JCA_6_Net Centric; JCA_6.3_Net Management; JCA_3.2_Engagement; JCA_3_Force Application; JCA_5_Command and Control; JCA_3.2.1_Kinetic Means; JCA_5.3_Planning
Communities of Interest:
Counter IED
Descriptor(s):
*FLUORINE COMPOUNDS, *ORGANIC SULFUR COMPOUNDS, *PEROXIDES, CHEMICAL PROPERTIES, CHEMICAL REACTIONS, ELECTROLYSIS, ESTERS, EXPLOSIVES, HALOGENATED HYDROCARBONS, INFRARED SPECTRA, MASS SPECTRA, NUCLEAR MAGNETIC RESONANCE, OXIDIZERS, SULFONATES, SYNTHESIS(CHEMISTRY)
Field(s)/Group(s):
Inorganic Chemistry
Report Date:
1965 Apr 01