INFRARED SPECTRA OF METAPHOSPHATE GLASSES.

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Abstract:

The infrared transmission spectra of binary alkali or alkaline-earth metaphosphate glasses have been determined. The glass systems include Li2O.P2O5, Na2O.P2O5, K2O.P2O5, Rb2O.P2O5, CaO.P2O5, SrO.P2O5, BaO.P2O5 and the devitrified K2O.P2O5. Three sampling techniques, namely, the thin film, the KBr-pellet and the reflection have been compared by their infrared spectra in the wavelength 2 to 15 microns. The IR spectra with identical results. Studies have been made on the possible re-orientation of the structure of Na2O.P2O5 glass prepared by extended period of melting, blowing into films and drawing into fibers without change in glass structure. A zigzag chain model of the sodium metaphosphate glass is derived from the X-ray scattering studies by Milberg and Daly Jour. of Chemical Physics U. S. A. 3q2966-2973 July 1963. Using the Wilson FG-matrix technique, a group theoretical analysis of the model has been carried out, with close agreements between the predicted normal frequencies and observed frequencies.

Author(s):
Su, Gouq-jen ; Shih, Chi-kai
Author Organization(s):
ROCHESTER UNIV N Y
Descriptive Note:
Technical rept. no. 1,
Supplementary Note:
Prepared in cooperation with Advanced Research Projects Agency, Washington, D. C. Doctoral thesis.
Annotation:
Infrared spectra of metaphosphate glasses.
Pagination:
0069

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Contract/Grant Number(s):
Nonr66819
 Subject Terms
Joint Capability Areas:
JCA_6.3.3_Spectrum Management; JCA_6_Net Centric; JCA_6.3_Net Management
Communities of Interest:
Advanced Electronics
Descriptor(s):
(*PHOSPHATE GLASS, INFRARED SPECTROSCOPY), (*INFRARED SPECTROSCOPY, PHOSPHATE GLASS), PHOSPHATES, LITHIUM COMPOUNDS, SODIUM COMPOUNDS, POTASSIUM COMPOUNDS, RUBIDIUM COMPOUNDS, CALCIUM COMPOUNDS, STRONTIUM COMPOUNDS, BARIUM COMPOUNDS, ALKALINE EARTH COMPOUNDS, ALKALI METAL COMPOUNDS, BROMIDES, TEST METHODS, MELTING, REFLECTION, X RAY SPECTROSCOPY
Report Date:
1964 Dec 01