STUDIES ON ISONITROSOKETONES,

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Abstract:

A study was undertaken of the behavior of isonitrosoacetone toward hydroxylamine in alkaline or acid media with the aim of contributing to the knowledge of the structure of condensation products obtained from isonitroso ketones when exposed to the effect of mineral acids or hydroxylamine hydrochloride. The results obtained by subjecting isonitrosoacetone to the action of hydroxylamine in a strongly alkaline medium, and to the action of hydrochloric acid are given. It was shown that the isonitroso compound is converted in the first case into aminomethylfurazan in an excellent yield, and in the second case into a condensation product whose structure is under investigation and whose brutto formula is C6H9N3O3. Author

Author(s):
Cusmano, S. ; Tiberio, T.
Author Organization(s):
REDSTONE SCIENTIFIC INFORMATION CENTER REDSTONE ARSENAL ALA
Supplementary Note:
Trans. of Gazzetta Chimica Italiana, 1951, v. 81, p. 106-116.
Annotation:
Isonitroso acetone - condensation reactions with hydroxylamine and with hydrochloric acid.
Pagination:
0014

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
RSIC-167
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*ACETONES, CONDENSATION REACTIONS), (*FURANS, CONDENSATION REACTIONS), ORGANIC NITROGEN COMPOUNDS, NITROGEN HETEROCYCLIC COMPOUNDS, MOLECULAR STRUCTURE, INORGANIC ACIDS, AMINES, ITALY
Report Date:
1964 Apr 22