CHEMISTRY OF RARE GAS COMPOUNDS.

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Abstract:

A number of properties have been determined for the stable xenon fluorides and oxyfluorides. In addition, efforts were made to prepare KrF4 and XeOF2 so that their properties could be determined but these efforts were not successful. The properties measured were melting point, vapor pressure, density, thermal stability and heat of formation. Average energies were calculated from the heats of formation for the XeF bond in the three known xenon fluorides. The strength of the XeF bond was found to be almost the same in XeF2 34.6 kcalmole, XeF4 30.5 kcalmole and XeF6 32.3 kcalmole. Author

Author(s):
Tannenbaum, S. ; Mahar, R. ; Crothamel, J. ; Lum, A. ; Castaldi, P.
Author Organization(s):
THIOKOL CHEMICAL CORP DENVILLE NJ REACTION MOTORS DIV
Descriptive Note:
Final rept. 2 Nov 64-1 Nov 65,
Annotation:
Chemistry of rare gas compounds.
Pagination:
0067

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
AFRPL-TR-66-14
Contract/Grant Number(s):
AF 04(611)-10379
Monitor Series:
TR-66-14
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*RARE GASES, CHEMICAL COMPOUNDS), SYNTHESIS(CHEMISTRY), XENON, FLUORIDES, KRYPTON, OXYFLUORIDES, HEAT OF FORMATION, MELTING POINT, VAPOR PRESSURE, DENSITY, THERMAL STABILITY, CHEMICAL BONDS, ENERGY, ULTRAVIOLET RADIATION, ELECTRIC DISCHARGES, PHOTOLYSIS, X RAY DIFFRACTION, INFRARED SPECTRA, HIGH TEMPERATURE, HIGH PRESSURE, NUCLEAR MAGNETIC RESONANCE, MASS SPECTROSCOPY, SPECTRUM ANALYZERS, RADIOACTIVE ISOTOPES, STORAGE, STABILITY, CALORIMETRY, CHEMICAL REACTIONS, AMMONIA
Field(s)/Group(s):
Polymer Chemistry, Atomic and Molecular Physics and Spectroscopy
Keyword(s):
KEL F, KRYPTON COMPOUNDS, MONEL METAL, TETRAFLUOROETHYLENE RESINS, TIME OF FLIGHT MASS SPECTROMETER, XENON DIFLUORIDE, XENON COMPOUNDS, XENON HEXAFLUORIDE, XENON TETRAFLUORIDE, XENON OXYTETRAFLUORIDE
Report Date:
1966 May 01