TRIPLET METHYLENE FORMATION ON PHOTOLYSIS OF KETENE AND DIAZOMETHANE,

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Abstract:

Results are presented which reconcile a recently-discovered anomaly between gas-phase and liquid-phase behavior of diazomethane-methylene radical systems, and which contrast the behavior of ketene and diazomethane systems. Author

Author(s):
Rabinovitch, B. S. ; Watkins, K. W. ; Ring, D. F.
Author Organization(s):
WASHINGTON UNIV SEATTLE DEPT OF CHEMISTRY
Annotation:
Triplet methylene formation on photolysis of ketene and diazomethane.
Pagination:
0007

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release

RECORD

Collection: TR
Identifying Numbers
Contract/Grant Number(s):
Nonr47736
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
(*KETENES, PHOTOCHEMICAL REACTIONS), (*PHOTOCHEMICAL REACTIONS, NITROGEN HETEROCYCLIC COMPOUNDS), METHANE, FREE RADICALS, PHASE STUDIES, GASES, LIQUIDS, ATOMIC ORBITALS, REACTION KINETICS, EXCITATION, ALKENES, ULTRAVIOLET RADIATION, PRESSURE
Keyword(s):
DIAZOMETHANE, SINGLET STATE, TRIPLET STATE
Report Date:
1964 Jan 01