VOLTAMMETRIC EVALUATION OF THE STABILITY OF TRICHLORIDE, TRIBROMIDE, AND TRIIODIDE IONS IN NITROMETHANE, ACETONE, AND ACETONITRILE,

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Abstract:

The formation constants of trichloride, tribromide, and triiodide ions in acetonitrile and tribromide and triiodide ions in nitromethane and in acetone have been evaluated from electrochemical data. In addition, lower limits for the formation constant of the trichloride ion in acetone and in nitromethane have been calculated. The order of stability of the trihalides in these three aprotic solvents is Cl3- Br3- I3-, the reverse of that found in water. Author

Author(s):
Nelson, Ivory V. ; Iwamoto, Reynold T.
Author Organization(s):
KANSAS UNIV LAWRENCE
Supplementary Note:
Reprint from Jnl. of Electroanalytical Chemistry, 6, pp. 218-221, 1964. (Copies supplied by DDC)
Annotation:
Reprint on the voltammetric evaluation of the stability of trichloride, tribromide, and triiodide ions in nitromethane, acetone and acetonitrile.
Pagination:
0004

Security Markings

DOCUMENT & CONTEXTUAL SUMMARY

Distribution:
Approved For Public Release, Document Partially Illegible
Distribution Statement:
Document Partially Illegible.

RECORD

Collection: TR
Identifying Numbers
Report Number(s):
AFOSR-64, 1516
Monitor Series:
64, 1516
 Subject Terms
Communities of Interest:
No COI(s) Identified
Descriptor(s):
*IONS, *ELECTROCHEMISTRY, *HALIDES, STABILITY, ORGANIC SOLVENTS, CHLORINE, HALOGENS, NITRATES, POLAROGRAPHIC ANALYSIS, KETONES, BROMINE, NITRILES, IONIZATION, IODINE, ORGANIC NITROGEN COMPOUNDS
Keyword(s):
acetonitrile, acetone, nitromethane
Report Date:
1963 Dec 01
Creation Date:
1964 Oct 15